A Tris(3‐pyridyl)stannane as a Building Block for Heterobimetallic Coordination Polymers and Supramolecular Cages

Cyclic polymers as a building block for cyclic brush polymers and gels

A novel tricyanoruthenium(III) building block for the construction of bimetallic coordination polymers.

Reaction of excess cyanide with a ruthenium(VI) nitrido complex bearing a tridentate Schiff base ligand produces a novel tricyanoruthenium(III) complex in which nucleophilic substitution of an imine hydrogen of the Schiff base by cyanide has occurred, this complex is a useful building block for the construction of 3d-Ru(III) magnetic materials.

Carboxylic acid-doped SBA-15 silica as a host for metallo-supramolecular coordination polymers.

The adsorption of a metallo-supramolecular coordination polymer (Fe-MEPE) in the cylindrical pores of SBA-15 silica with pure and carboxylic acid (CA) carrying pore walls has been studied. Fe-MEPE is an intrinsically stiff polycation formed by complexation of Fe(II)-acetate with an uncharged ditopic bis-terpyridine ligand. The adsorption affinity and kinetics of the Fe-MEPE chains is strongly e...

The Diphosphorus Complex [Cp2Mo2(CO)4(η2‐P2)] as a Building Block for the Synthesis of Mixed‐Hybrid Coordination Polymers

The three-component reaction of the tetrahedral diphosphorus complex [Cp2Mo2(CO)4(η2-P2)] (1), with Ag[BF4] (2) in the presence of 2,2'-bipyrimidine (3) leads to the formation of the two novel two-dimensional networks 4 and 5. Compound 4 is a new two-dimensional organometallic-organic hybrid polymer, while derivative 5 represents a unique two-dimensional organometallic-inorganic-organic hybrid ...

Coordination polymers with macrocyclic cages and pockets within their backbones.

The reaction between the flexible ligand (1,4-bis(pyridine-2-yl-methanethio)benzene) and Ag+ produces two novel coordination polymers with macrocyclic cages or pockets contained within their backbones, depending upon the ratio of starting materials.